Buildup of Triplet-State Population in Operating TQ1:PC₇₁BM Devices Does Not Limit Their Performance

Triplet generation in organic solar cells has been considered a major loss channel. Determining the density of the triplet-state population in an operating device is challenging. Here, we employ transient absorption (TA) spectroscopy on the quinoxaline–thiophene copolymer TQ1 blended with PC₇₁BM, quantify the transient charge and triplet-state densities, and parametrize their generation and recombination dynamics. The charge recombination parameters reproduce the experimentally measured current–voltage characteristics in charge carrier drift-diffusion simulations, and they yield the steady-state charge densities. We demonstrate that triplets are formed by both geminate and nongeminate recombination of charge carriers and decay primarily by triplet–triplet annihilation. Using the charge densities in the rate equations describing triplet-state dynamics, we find that triplet-state densities in devices are in the range of charge carrier densities. Despite this substantial triplet-state buildup, TQ1:PC₇₁BM devices exhibit only moderate geminate recombination and significantly reduced nongeminate charge recombination, with reduction factors between 10^–4 and 10^–3 compared to Langevin recombination.