Rosin and cellulose nanocrystals (CNCs) are easily extracted from
agricultural pines/conifers and natural cellulose, and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) is extracted from agricultural
corn stalks, etc. In this study, PHBV and CNC-grafted rosin (CNC-R)
hybrids were successfully fabricated by an efficient solution casting.
The nanocomposites with a homogenous microstructure were transparent
and had strong barrier resistances to water vapor and two food simulants.
The synchronous enchantments in mechanical strength/toughness and
thermal stability of nanocomposite films were achieved by addition
of CNC-R. The T0 increased by 31.2 °C
for the film with 10 wt % CNC-R; meanwhile, the tensile strength and
elongation to break were improved by 107.9 and 43.9% for the sample
using 5 wt % CNC-R, respectively. Also, compared to neat PHBV, the
nanocomposites with 5 wt % CNC-R exhibited excellent barrier properties,
antibacterial activity (100.0% antibacterial ratio), and lower migration
levels for both food simulants. The appearance of coated grapes with
10 wt % CNC-R nanocomposites at the 11th day was the best compared
to those of PHBV and its nanocomposites with a low CNC-R content (1–3
wt %). Thus, our nanocomposites with CNC-R showed a significant application
in packaged grape by extended shelf life and had potential applications
in bioactive food packaging materials.