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Atomically Dispersed Nickel Sites for Selective Electroreduction of CO2
journal contribution
posted on 2019-12-10, 11:44 authored by Fang Li, Song Hong, Tai-Sing Wu, Xin Li, Justus Masa, Yun-Liang Soo, Zhenyu SunElectrocatalytic CO2 reduction at its point
of generation
to form fuels and commodity chemicals using electricity from renewable
sources is an appealing strategy for decreasing net anthropogenic
CO2 emissions and mitigating global warming. CO2 reduction is however a kinetically slow and energy intensive reaction
with a wide range of possible products. Therefore, the development
of highly selective, energy-efficient, and cost-effective electrocatalysts
is required to accelerate this kinetically sluggish process. We report
facile synthesis of atomically dispersed Ni sites supported on nitrogen-doped
carbon (Ni/NC), which significantly facilitates selective electrochemical
CO2 reduction to CO with a Faradaic efficiency reaching
92.3% at a low overpotential of 0.69 V (relative to the formal redox
potential of CO2 reduction to CO, E0redox = −0.11 V versus reversible hydrogen
electrode, pH 0), surpassing Ni particles and many other reported
metal-based catalysts. This study thus unveils a platform of activating
Ni sites for selective reduction of CO2.