ol503698s_si_001.cif (18.67 kB)
Asymmetric Dearomatization of 1‑Aminonaphthalene Derivatives by Gold-Catalyzed Intramolecular Double C–C Bond Formation
dataset
posted on 2015-02-06, 00:00 authored by Junko Oka, Ryuichi Okamoto, Keiichi Noguchi, Ken TanakaIt
has been established that a cationic gold(I)/axially chiral
biaryl bisphosphine complex catalyzes asymmetric dearomatization of
1-aminonaphthalene derivatives by the intramolecular double C–C
bond formation. Two different dearomatization products were obtained
depending on the substituents on the benzyl groups at the alkyne termini.