ic701614c_si_008.cif (85.96 kB)
An Unknown Coordination Mode of the Phosphite Unit and a Carbon-Free Heterocycle in Two Different Heterobimetallic Alumophosphites
dataset
posted on 2007-12-10, 00:00 authored by A. Paulina Gómora-Figueroa, Vojtech Jancik, Raymundo Cea-Olivares, Rubén A. ToscanoThe unique alumophosphite reagent LAl(SH)(μ-O)P(OEt)2 was prepared and used for the synthesis of the
heterobimetallic alumophosphites [{κ2-S,P-LAl(S)(μ-O)P(OEt)2}2Zn] and [{κ4-S,O,O-LAl(SLi)(μ-O)P(OEt)2}2]. The
first contains a rare example of two carbon-free five-membered heterocycles (Al−S−Zn−P−O) connected in a spiro
fashion through the zinc atom, whereas the second possesses an unknown example of a coordination environment
of a phosphite unit M−O−P(μ-OEt)2M with an uncoordinated lone electron pair on the phosphorus center.