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All-Solid-State Reduced Graphene Oxide Supercapacitor with Large Volumetric Capacitance and Ultralong Stability Prepared by Electrophoretic Deposition Method
journal contribution
posted on 2015-01-21, 00:00 authored by Mei Wang, Le Dai Duong, Nguyen
Thi Mai, Sanghoon Kim, Youngjun Kim, Heewon Seo, Ye Chan Kim, Woojin Jang, Youngkwan Lee, Jonghwan Suhr, Jae-Do NamPortable
energy storage devices have gained special attention due
to the growing demand for portable electronics. Herein, an all-solid-state
supercapacitor is successfully fabricated based on a poly(vinyl alcohol)-H3PO4 (PVA–H3PO4) polymer
electrolyte and a reduced graphene oxide (RGO) membrane electrode
prepared by electrophoretic deposition (EPD). The RGO electrode fabricated
by EPD contains an in-plane layer-by-layer alignment and a moderate
porosity that accommodate the electrolyte ions. The all-solid-state
RGO supercapacitor is thoroughly tested to give high specific volumetric
capacitance (108 F cm–3) and excellent energy and
power densities (7.5 Wh cm–3 and 2.9 W cm–3, respectively). In addition, the all-solid-state RGO supercapacitor
exhibits an ultralong lifetime for as long as 180 days (335 000
cycles), which is an ultrahigh cycling capability for a solid-state
supercapacitor. The RGO is also tested for being used as a transparent
supercapacitor electrode demonstrating its possible use in various
transparent optoelectronic devices. Due to the facile scale-up capability
of the EPD process and RGO dispersion, the developed all-solid-state
supercapacitor is highly applicable to large-area portable energy
storage devices.
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Large Volumetric Capacitanceelectrophoretic depositionultralong lifetimesupercapacitor electrodegraphene oxideElectrophoretic Deposition MethodPortable energy storage deviceselectrolyte ionsRGO electrodecmPVAUltralong StabilityEPD processultrahigh cycling capabilitymembrane electrodeRGO dispersionoptoelectronic devicesenergy storage devices
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