ol9b03848_si_001.pdf (4.82 MB)
Alkyl Halides via Visible Light Mediated Dehalogenation
journal contribution
posted on 2019-11-14, 14:41 authored by Manjula
D. Rathnayake, Jimmie D. WeaverNet selective bromination and chlorination of activated
C–H
bonds can be effected in generally high yield via a simple perhalogenation/dehalogenation
sequence. The photochemical reductions require no photocatalyst, relying
instead on the formation of an electron donor–acceptor complex
of the substrate and reductant, or alternatively autophotocatalysis.
Some reactions proceed despite any apparent photon absorption, serving
as a cautionary tale for other photochemical reactions involving amines.
Mechanistic experiments provide an explanation for this observation.