ja8b13251_si_001.pdf (23.27 MB)
Alkenyl Exchange of Allylamines via Nickel(0)-Catalyzed C–C Bond Cleavage
Version 2 2019-02-11, 15:24
Version 1 2019-02-08, 20:19
journal contribution
posted on 2019-02-08, 00:00 authored by Chao Fan, Xin-Yang Lv, Li-Jun Xiao, Jian-Hua Xie, Qi-Lin ZhouA functional group
exchange reaction between allylamines
and alkenes via nickel-catalyzed CC bond cleavage and formation
was developed. This reaction provides a novel protocol, which does
not require the use of unstable imine substrates, for the synthesis
of allylamines, which are widely used in the production of fine
chemicals, pharmaceuticals, and agrochemicals.
