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Ag2S‑Sensitized NiO–ZnO Heterostructures with Enhanced Visible Light Photocatalytic Activity and Acetone Sensing Property
journal contribution
posted on 2019-07-31, 08:14 authored by Adil Shafi, Nafees Ahmad, Saima Sultana, Suhail Sabir, Mohammad Zain KhanVisible
light-driven Ag2S-grafted NiO–ZnO ternary
nanocomposites are synthesized using a facile and cost-effective homogeneous
precipitation method. The structural, morphological, and optical properties
were extensively studied, confirming the formation of ternary nanocomposites.
The surface area of the synthesized nanocomposites was calculated
by electrochemical double-layer capacitance (Cdl). Ternary Ag2S/NiO–ZnO nanocomposites
showed excellent visible light photocatalytic property which increases
further with the concentration of Ag2S. The maximum photocatalytic
activity was shown by 8% Ag2S/NiO–ZnO with a RhB
degradation efficiency of 95%. Hydroxyl and superoxide radicals were
found to be dominant species for photodegradation of RhB, confirmed
by scavenging experiments. It is noteworthy that the recycling experiments
demonstrated high stability and recyclable nature of the photocatalyst.
Moreover, the electrochemical results indicated that the prepared
nanocomposite exhibits remarkable activity toward detection of acetone.
The fabricated nanocomposite sensor showed high sensitivity (4.0764 μA
mmol L–1 cm–2) and a lower detection
limit (0.06 mmol L–1) for the detection of acetone.
The enhanced photocatalytic and the sensing property of Ag2S/NiO–ZnO can be attributed to the synergistic effects of
strong visible light absorption, excellent charge separation, and
remarkable surface properties.
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recycling experimentssurface areaternary nanocompositesRhB degradation efficiencylight photocatalytic propertyelectrochemical resultslight absorptiondetectionsuperoxide radicalsAg 2 Selectrochemical double-layer capacitancenanocomposite exhibitsC dlcharge separationsurface propertiesnanocomposite sensorEnhanced Visible Light Photocatalytic Activityprecipitation methodphotocatalytic activity
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