A Novel Tin-Doped Titanium Oxide Nanocomposite for Efficient Photo-Anodic Water Splitting

Herein, we report the expedient synthesis of new nanocomposite Sn_0.39Ti_0.61O₂·TiO₂ flakes using simple sol–gel and calcination methods. In order to prepare this material, first, we generated a polymeric gel using cost-effective and easily accessible precursors such as SnCl₄, titanium isopropoxide, and tetrahydrofuran (THF). A small amount of triflic acid was used to initiate THF polymerization. The calcination of the resulting gel at 500 °C produced a Sn–Ti bimetallic nanocomposite. This newly synthesized Sn_0.39Ti_0.61O₂·TiO₂ was characterized by X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and UV–visible spectroscopy. The photoelectrochemical (PEC) studies were performed for the first time using Sn_0.39Ti_0.61O₂·TiO₂ coated over fluorine-doped tin oxide (FTO) under simulated 1 sun solar radiation. The chronoamperometric study of the Sn_0.39Ti_0.61O₂·TiO₂/FTO revealed the repeatable and substantially higher photocurrent for the oxygen evolution reaction (OER) when compared to only TiO₂. Moreover, the synthesized material exhibited high stability both in the presence and absence of light. The photocatalytic studies suggested that the sol–gel-synthesized Sn_0.39Ti_0.61O₂·TiO₂ can be efficiently used as a photoanode in the water-splitting reaction.