ol025678t_si_002.pdf (466.23 kB)
A Novel Photorearrangement of a Cyclohexadiene Derivative of C60
journal contribution
posted on 2002-03-13, 00:00 authored by Sho-ichi Iwamatsu, Periya S. Vijayalakshmi, Masanori Hamajima, Cherumuttathu H. Suresh, Nobuaki Koga, Toshiyasu Suzuki, Shizuaki MurataPhotorearrangement of tetraalkoxycarbonyl-substituted cyclohexadiene derivatives of C60 yields not only well-known bis(fulleroid) but also
bis(methano)fullerene. Existence of a labile and structurally new intermediate is observed in the reaction mixture. The discovery of the compound
suggests the existence of another possible pathway giving those two products other than the widely accepted [4 + 4]/[2 + 2 + 2] mechanism.