A Fluorobenzene Adduct of Ti(IV), and Catalytic Carboamination to Prepare α,β-Unsaturated Imines and Triaryl-Substituted Quinolines

A rare fluorobenzene adduct of group 4, [(nacnac)TiNAr(FC₆H₅)][B(C₆F₅)₄] (nacnac- = [ArNC(^tBu)]₂CH, Ar = 2,6-ⁱPr₂C₆H₃), has been isolated and structurally characterized. This highly electron-deficient system engages readily in imine metathesis and catalyzes carboamination reactions involving diphenylacetylene and aldimines to afford α,β-unsaturated imines as well as triaryl-substituted quinolines. The latter product results from cyclization of the corresponding electron-rich α,β-unsaturated imine.