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A Facile Total Synthesis of Hainanensine via an Unusual Rearrangement−Annulation Cascade

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posted on 2010-04-16, 00:00 authored by Zhi-Wei Zhang, Wei-Dong Z. Li
A facile total synthesis of hainanensine (1), a structurally unique Cephalotaxus alkaloid, via an effective acid-mediated rearrangement/Friedel−Crafts annulation cascade (7a/7b → 8a/8b), is described.

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    Organic Letters

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    Keywords

    UnusualHainanensineannulationsynthesishainanensineCephalotaxus alkaloidFacileCascadeRearrangementcascaderearrangementSynthesi

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