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A Facile Pd(0)-Catalyzed Regio- and Stereoselective Diamination of Conjugated Dienes and Trienes
journal contribution
posted on 2007-01-31, 00:00 authored by Haifeng Du, Baoguo Zhao, Yian ShiThis paper describes a novel diamination process using di-t-butyldiaziridinone as the nitrogen source and Pd(PPh3)4 as catalyst. A wide variety of conjugated dienes and trienes can be effectively diaminated in good yields with high regio- and stereoselectivities in short reaction time.