A Facile Pd(0)-Catalyzed Regio- and Stereoselective Diamination of Conjugated Dienes and Trienes

2007-01-31T00:00:00Z (GMT) by Haifeng Du Baoguo Zhao Yian Shi
This paper describes a novel diamination process using di-t-butyldiaziridinone as the nitrogen source and Pd(PPh3)4 as catalyst. A wide variety of conjugated dienes and trienes can be effectively diaminated in good yields with high regio- and stereoselectivities in short reaction time.