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A Copper-Catalyzed Three-Component Reaction of Triethoxysilanes, Sulfur Dioxide, and Hydrazines
journal contribution
posted on 2014-08-01, 00:00 authored by Xianbo Wang, Lijun Xue, Zhiyong WangA three-component reaction of triethoxysilanes,
sulfur dioxide,
and hydrazines catalyzed by copper(II) acetate is reported, leading
to N-aminosulfonamides in good yields.
Not only triethoxy(aryl)silanes but also triethoxy(alkyl)silanes
are compatible during the process of insertion of sulfur dioxide.
Additionally, diethoxydiarylsilanes are suitable under
the conditions as well.