ol016200c_si_001.cif (13.12 kB)

A 4 + 3 Cycloaddition Approach to the Synthesis of Spatol. A Formal Total Synthesis of Racemic Spatol

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posted on 2001-07-07, 00:00 authored by Michael Harmata, Paitoon Rashatasakhon

A formal total synthesis of racemic spatol is presented. The key steps involved a 4 + 3 cycloaddition of a halogenated cyclopentenyl cation to cyclopentadiene and a quasi-Favorskii rearrangement.

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Keywords

Racemic Spatol cyclopentenyl cation cyclopentadiene 3 cycloaddition racemic spatol synthesis 3 Cycloaddition Approach Formal rearrangement Synthesi

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CC BY-NC 4.0

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