%0 Generic
%A Duan, Longhui
%A Zhao, Kun
%A Wang, Zhonggui
%A Zhang, Feng-Lian
%A Gu, Zhenhua
%D 2019
%T Enantioselective Ring-Opening/Oxidative Phosphorylation
and P‑Transfer Reaction of Cyclic Diaryliodoniums
%U https://acs.figshare.com/articles/dataset/Enantioselective_Ring-Opening_Oxidative_Phosphorylation_and_P_Transfer_Reaction_of_Cyclic_Diaryliodoniums/9929837
%R 10.1021/acscatal.9b03454.s004
%2 https://acs.figshare.com/ndownloader/files/17869133
%K Cyclic Diaryliodoniums
%K atropisomeric phosphine oxides
%K 18 O-Labeled experiments
%K BuLi-mediated P-transfer reaction
%K Computational studies
%K cyclic diaryliodonium salts
%K formation
%K diarylphosphine oxides
%K phosphine oxide transfer
%K bond
%X A Cu-catalyzed
enantioselective ring-opening/oxidative phosphorylation
reaction of cyclic diaryliodonium salts and diarylphosphine oxides
in the presence of TEMPO was reported. 18O-Labeled experiments
showed that the reaction proceeded via oxidation, followed by C–O
bond formation. Furthermore, atropisomeric phosphine oxides were prepared
via a t-BuLi-mediated P-transfer reaction. Computational
studies elucidated that the phosphine oxide transfer was through a
concerted C–P bond formation and P–O bond-dissociation
process.
%I ACS Publications