Li, Jian Rao, Weidong Wang, Shun-Yi Ji, Shun-Jun Nickel-Catalyzed Defluorinative Reductive Cross-Coupling Reaction of <i>gem-</i>Difluoroalkenes with Thiosulfonate or Selenium Sulfonate A nickel-catalyzed defluorinative reductive cross-coupling of <i>gem</i>-difluoroalkenes with thiosulfonate or selenosulfonates is described. The reaction involves the formation of thiolated or selenylated monofluoroolefins via regioselective C–F bond cleavage and C–S or C–Se bond formation and features easily available substrates, mild reaction conditions, and high <i>E</i>-selectivity. One of the derivatives by further cross coupling with PhMgBr exhibited an aggregation-induced emission enhancement effect. reaction conditions;selenosulfonate;selectivity;Nickel-Catalyzed Defluorinative Reductive Cross-Coupling Reaction;Thiosulfonate;thiolated;regioselective;Selenium Sulfonate;difluoroalkene;derivative;thiosulfonate;selenylated monofluoroolefins;formation;PhMgBr;gem;substrate;Difluoroalkene;aggregation-induced emission enhancement effect;nickel-catalyzed defluorinative reductive cross-coupling;cleavage;bond 2019-08-28
    https://acs.figshare.com/articles/journal_contribution/Nickel-Catalyzed_Defluorinative_Reductive_Cross-Coupling_Reaction_of_i_gem-_i_Difluoroalkenes_with_Thiosulfonate_or_Selenium_Sulfonate/9742262
10.1021/acs.joc.9b01387.s001