10.1021/acs.inorgchem.9b00502.s001
Zhenxin Zhang
Zhenxin
Zhang
Satoshi Ishikawa
Satoshi
Ishikawa
Qianqian Zhu
Qianqian
Zhu
Toru Murayama
Toru
Murayama
Masahiro Sadakane
Masahiro
Sadakane
Michikazu Hara
Michikazu
Hara
Wataru Ueda
Wataru
Ueda
Redox-Active Zeolitic Transition Metal Oxides Based
on ε‑Keggin Units for Selective Oxidation
American Chemical Society
2019
form ethyl pyruvate
redox properties
ethyl lactate oxidation
zeolitic transition metal oxides
material
Redox-Active Zeolitic Transition Metal Oxides
O 2
ε- Keggin iron molybdates
Redox-active zeolitic transition metal oxides
2019-04-23 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Redox-Active_Zeolitic_Transition_Metal_Oxides_Based_on_Keggin_Units_for_Selective_Oxidation/8028944
The design and development of zeolitic
transition metal oxides for selective oxidation are interesting due
to the combination of the redox properties and microporosities. Redox-active
zeolitic transition metal oxides based on ε-Keggin iron molybdates
were synthesized. O<sub>2</sub> can be activated by the materials
via an electron-transfer-based process, and the materials can be oxidized
even at room temperature. The materials are oxidized and reduced reversibly
while the crystal structures are maintained. V is uniformly incorporated
in the materials without changing the basic structures, and the redox
properties of the materials are tuned by V. The materials are used
as robust catalysts for ethyl lactate oxidation to form ethyl pyruvate
using O<sub>2</sub> as an oxidant.