Azaindenocorannulenes: Synthesis, Properties, and Chirality TianXiaoqi RochLoïc M. VanthuyneNicolas XuJun BaldridgeKim K. SiegelJay S. 2019 Palladium-catalyzed intramolecular arylation provides bowl-shaped azaindenocorannulenes <b>7</b>–<b>9</b>. Crystals of <b>8</b> show bowl-in-bowl columnar stacking. A substituent model rationalizes the first reduction potential of 18 related molecular bowls. The absolute configurations of bowls <b>7</b> and <b>9</b> are correlated with VCD and ECD spectra. The bowl inversion barrier of <b>9</b> (>190 kJ/mol) shows it to be more inert configurationally than chiral biaryl, phosphenes, or [<i>n</i>]­helicenes.