%0 Journal Article %A Ma, Cong %A Zhao, Chuan-Qi %A Xu, Xue-Tao %A Li, Zhao-Ming %A Wang, Xiang-Yang %A Zhang, Kun %A Mei, Tian-Sheng %D 2019 %T Nickel-Catalyzed Carboxylation of Aryl and Heteroaryl Fluorosulfates Using Carbon Dioxide %U https://acs.figshare.com/articles/journal_contribution/Nickel-Catalyzed_Carboxylation_of_Aryl_and_Heteroaryl_Fluorosulfates_Using_Carbon_Dioxide/7893170 %R 10.1021/acs.orglett.9b00836.s001 %2 https://acs.figshare.com/ndownloader/files/14701703 %K Dioxide %K Fluorosulfate %K C 1 synthon %K arene carboxylic acids %K Carboxylation %K Nickel-catalyzed %K Heteroaryl %K carboxylation %K phenol %K method %K fluorosulfate %K importance %K Nickel-Catalyzed %K heteroaryl %K Aryl %K fluorosulfation %K CO 2 %K yield %K aryl %K one-pot %X The development of efficient and practical methods to construct carboxylic acids using CO2 as a C1 synthon is of great importance. Nickel-catalyzed carboxylation of aryl fluorosulfates and heteroaryl fluorosulfates with CO2 is described, affording arene carboxylic acids with good to excellent yields under mild conditions. In addition, a one-pot phenol fluorosulfation/carboxylation is developed. %I ACS Publications