%0 Journal Article
%A Ma, Cong
%A Zhao, Chuan-Qi
%A Xu, Xue-Tao
%A Li, Zhao-Ming
%A Wang, Xiang-Yang
%A Zhang, Kun
%A Mei, Tian-Sheng
%D 2019
%T Nickel-Catalyzed Carboxylation of Aryl and Heteroaryl
Fluorosulfates Using Carbon Dioxide
%U https://acs.figshare.com/articles/journal_contribution/Nickel-Catalyzed_Carboxylation_of_Aryl_and_Heteroaryl_Fluorosulfates_Using_Carbon_Dioxide/7893170
%R 10.1021/acs.orglett.9b00836.s001
%2 https://acs.figshare.com/ndownloader/files/14701703
%K Dioxide
%K Fluorosulfate
%K C 1 synthon
%K arene carboxylic acids
%K Carboxylation
%K Nickel-catalyzed
%K Heteroaryl
%K carboxylation
%K phenol
%K method
%K fluorosulfate
%K importance
%K Nickel-Catalyzed
%K heteroaryl
%K Aryl
%K fluorosulfation
%K CO 2
%K yield
%K aryl
%K one-pot
%X The development of
efficient and practical methods to construct
carboxylic acids using CO2 as a C1 synthon is of great
importance. Nickel-catalyzed carboxylation of aryl fluorosulfates
and heteroaryl fluorosulfates with CO2 is described, affording
arene carboxylic acids with good to excellent yields under mild conditions.
In addition, a one-pot phenol fluorosulfation/carboxylation is developed.
%I ACS Publications