10.1021/acs.orglett.9b00836.s001
Cong Ma
Cong
Ma
Chuan-Qi Zhao
Chuan-Qi
Zhao
Xue-Tao Xu
Xue-Tao
Xu
Zhao-Ming Li
Zhao-Ming
Li
Xiang-Yang Wang
Xiang-Yang
Wang
Kun Zhang
Kun
Zhang
Tian-Sheng Mei
Tian-Sheng
Mei
Nickel-Catalyzed Carboxylation of Aryl and Heteroaryl
Fluorosulfates Using Carbon Dioxide
American Chemical Society
2019
Dioxide
Fluorosulfate
C 1 synthon
arene carboxylic acids
Carboxylation
Nickel-catalyzed
Heteroaryl
carboxylation
phenol
method
fluorosulfate
importance
Nickel-Catalyzed
heteroaryl
Aryl
fluorosulfation
CO 2
yield
aryl
one-pot
2019-03-26 11:37:18
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Nickel-Catalyzed_Carboxylation_of_Aryl_and_Heteroaryl_Fluorosulfates_Using_Carbon_Dioxide/7893170
The development of
efficient and practical methods to construct
carboxylic acids using CO<sub>2</sub> as a C1 synthon is of great
importance. Nickel-catalyzed carboxylation of aryl fluorosulfates
and heteroaryl fluorosulfates with CO<sub>2</sub> is described, affording
arene carboxylic acids with good to excellent yields under mild conditions.
In addition, a one-pot phenol fluorosulfation/carboxylation is developed.