10.1021/acs.orglett.9b00836.s001 Cong Ma Cong Ma Chuan-Qi Zhao Chuan-Qi Zhao Xue-Tao Xu Xue-Tao Xu Zhao-Ming Li Zhao-Ming Li Xiang-Yang Wang Xiang-Yang Wang Kun Zhang Kun Zhang Tian-Sheng Mei Tian-Sheng Mei Nickel-Catalyzed Carboxylation of Aryl and Heteroaryl Fluorosulfates Using Carbon Dioxide American Chemical Society 2019 Dioxide Fluorosulfate C 1 synthon arene carboxylic acids Carboxylation Nickel-catalyzed Heteroaryl carboxylation phenol method fluorosulfate importance Nickel-Catalyzed heteroaryl Aryl fluorosulfation CO 2 yield aryl one-pot 2019-03-26 11:37:18 Journal contribution https://acs.figshare.com/articles/journal_contribution/Nickel-Catalyzed_Carboxylation_of_Aryl_and_Heteroaryl_Fluorosulfates_Using_Carbon_Dioxide/7893170 The development of efficient and practical methods to construct carboxylic acids using CO<sub>2</sub> as a C1 synthon is of great importance. Nickel-catalyzed carboxylation of aryl fluorosulfates and heteroaryl fluorosulfates with CO<sub>2</sub> is described, affording arene carboxylic acids with good to excellent yields under mild conditions. In addition, a one-pot phenol fluorosulfation/carboxylation is developed.