Corannurylene Pentapetalae Dong Meng Guogang Liu Chengyi Xiao Yanjun Shi Lei Zhang Lang Jiang Kim K. Baldridge Yan Li Jay S. Siegel Zhaohui Wang 10.1021/jacs.9b00053.s002 https://acs.figshare.com/articles/dataset/Corannurylene_Pentapetalae/7863521 Despite the great advances in the synthesis of diverse nonplanar graphenoids, investigations into the relationship between structural features and intermolecular interactions still present significant challenges. Herein, the novel nonplanar graphenoid structure, corannurylene pentapetalae (CRP), obtained via bottom-up syntheses of hybridization between perylene diimide (PDI) planar fragments and a corannulene curved core, is presented. Single crystal studies reveal a <i>D</i><sub>5</sub>-symmetric as well as a <i>C</i><sub>2</sub>-symmetric graphenoid corannurylene pentapetalae. The <i>D</i><sub>5</sub>-symmetric structure has a unique honeycomb lattice with two chiral honeycomb layers alternately stacked, whereas the <i>C</i><sub>2</sub>-symmetric CRP forms dimer units via π–π stacking. Transistor devices demonstrate that, without any π–π stacking, the honeycomb lattice of the <i>D</i><sub>5</sub>-symmetric CRP has the potential to also facilitate electron transport. 2019-03-08 00:00:00 C 2 D 5 Single crystal studies chiral honeycomb layers honeycomb lattice graphenoid corannurylene pentapetalae CRP forms dimer units novel nonplanar graphenoid structure PDI