10.1021/acscentsci.8b00845.s003
Tuo Kang
Tuo
Kang
Yalong Wang
Yalong
Wang
Feng Guo
Feng
Guo
Chenghao Liu
Chenghao
Liu
Jianghui Zhao
Jianghui
Zhao
Jin Yang
Jin
Yang
Hongzhen Lin
Hongzhen
Lin
Yejun Qiu
Yejun
Qiu
Yanbin Shen
Yanbin
Shen
Wei Lu
Wei
Lu
Liwei Chen
Liwei
Chen
Self-Assembled Monolayer Enables Slurry-Coating of
Li Anode
American Chemical Society
2019
Li metal
SAM
Self-Assembled Monolayer Enables Slurry-Coating
SFG
aliphatic phosphonic acid molecules self-assemble
Li metal surface
DOD
long-chain aliphatic phosphonic acid
slurry-coated Li anode exhibits
1 C rate
Li Anode Li metal
CNT
sum-frequency generation spectroscopy
2019-02-12 15:35:02
Media
https://acs.figshare.com/articles/media/Self-Assembled_Monolayer_Enables_Slurry-Coating_of_Li_Anode/7707725
Li metal has long
been considered as the ultimate anodic material
for high-energy-density batteries. Protection of Li metal in electrochemical
cycling and in the manufacturing environment is critical for practical
applications. Here, we present the passivation of the Li metal–carbon
nanotube (CNT) composite with molecular self-assembly of a long-chain
aliphatic phosphonic acid. The dynamics of the self-assembly process
is investigated with sum-frequency generation spectroscopy (SFG).
The aliphatic phosphonic acid molecules self-assemble on the Li metal
surface via the lithium phosphate bonding, while the well-aligned
long chains of the molecules help to prevent corrosion of lithium
by oxygen and water in the air. As a result, the self-assembled monolayer
(SAM) passivated Li–CNT composite displays excellent stability
in dry or even humid air, and could be slurry-coated with organic
solvents. The resulting slurry-coated Li anode exhibits a high Coulombic
efficiency of 98.8% under a 33% depth of discharge (DOD) at a 1C rate
in full battery cycling. The concept of molecular self-assembly on
Li metal and the stability of the resulting SAM layer open vast possibilities
of designed reagents for surface passivation of Li, which may eventually
pave the way for practical application of Li metal in secondary batteries.