10.1021/jacs.8b13251.s001
Chao Fan
Chao
Fan
Xin-Yang Lv
Xin-Yang
Lv
Li-Jun Xiao
Li-Jun
Xiao
Jian-Hua Xie
Jian-Hua
Xie
Qi-Lin Zhou
Qi-Lin
Zhou
Alkenyl
Exchange of Allylamines via Nickel(0)-Catalyzed
C–C Bond Cleavage
American Chemical Society
2019
alkene
pharmaceutical
Allyl
group exchange reaction
chemical
novel protocol
imine substrates
synthesis
allyl
nickel-catalyzed
agrochemical
formation
Cleavage
Alkenyl Exchange
Bond
cleavage
bond
2019-02-08 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Alkenyl_Exchange_of_Allyl_amines_via_Nickel_0_-Catalyzed_C_C_Bond_Cleavage/7697945
A functional group
exchange reaction between allylamines
and alkenes via nickel-catalyzed CC bond cleavage and formation
was developed. This reaction provides a novel protocol, which does
not require the use of unstable imine substrates, for the synthesis
of allylamines, which are widely used in the production of fine
chemicals, pharmaceuticals, and agrochemicals.