Kaźmierczak, Joanna Kuciński, Krzysztof Lewandowski, Dariusz Hreczycho, Grzegorz Ru-Catalyzed Dehydrogenative Silylation of POSS-Silanols with Hydrosilanes: Its Introduction to One-Pot Synthesis A commercially available and stable ruthenium dodecacarbonyl catalyst (Ru<sub>3</sub>(CO)<sub>12</sub>) allows very efficient and convenient access to functionalized silsesquioxanes (SQs) containing siloxane moiety (Si–O–Si) via dehydrogenative coupling of POSS-silanols with hydrosilanes. With the aid of SiH-containing silsesquioxanes, an unprecedented one-pot procedure has been revealed, and the usefulness of this approach was demonstrated by the synthesis of various derivatives via O-silylation, as well as CC and CN hydrosilylation. dehydrogenative;one-pot procedure;Introduction;functionalized silsesquioxanes;usefulness;Hydrosilane;SiH-containing silsesquioxanes;siloxane moiety;POSS-silanol;O-silylation;access;derivative;hydrosilane;approach;POSS-Silanol;CO;hydrosilylation;Ru-Catalyzed Dehydrogenative Silylation;Ru 3;aid;ruthenium dodecacarbonyl catalyst;SQ;One-Pot Synthesis;synthesis 2019-01-10
    https://acs.figshare.com/articles/journal_contribution/Ru-Catalyzed_Dehydrogenative_Silylation_of_POSS-Silanols_with_Hydrosilanes_Its_Introduction_to_One-Pot_Synthesis/7575587
10.1021/acs.inorgchem.8b02645.s001