%0 Journal Article
%A Kaźmierczak, Joanna
%A Kuciński, Krzysztof
%A Lewandowski, Dariusz
%A Hreczycho, Grzegorz
%D 2019
%T Ru-Catalyzed Dehydrogenative Silylation of POSS-Silanols
with Hydrosilanes: Its Introduction to One-Pot Synthesis
%U https://acs.figshare.com/articles/journal_contribution/Ru-Catalyzed_Dehydrogenative_Silylation_of_POSS-Silanols_with_Hydrosilanes_Its_Introduction_to_One-Pot_Synthesis/7575587
%R 10.1021/acs.inorgchem.8b02645.s001
%2 https://acs.figshare.com/ndownloader/files/14072375
%K dehydrogenative
%K one-pot procedure
%K Introduction
%K functionalized silsesquioxanes
%K usefulness
%K Hydrosilane
%K SiH-containing silsesquioxanes
%K siloxane moiety
%K POSS-silanol
%K O-silylation
%K access
%K derivative
%K hydrosilane
%K approach
%K POSS-Silanol
%K CO
%K hydrosilylation
%K Ru-Catalyzed Dehydrogenative Silylation
%K Ru 3
%K aid
%K ruthenium dodecacarbonyl catalyst
%K SQ
%K One-Pot Synthesis
%K synthesis
%X A commercially available and stable
ruthenium dodecacarbonyl catalyst
(Ru3(CO)12) allows very efficient and convenient
access to functionalized silsesquioxanes (SQs) containing siloxane
moiety (Si–O–Si) via dehydrogenative coupling of POSS-silanols
with hydrosilanes. With the aid of SiH-containing silsesquioxanes,
an unprecedented one-pot procedure has been revealed, and the usefulness
of this approach was demonstrated by the synthesis of various derivatives
via O-silylation, as well as CC and CN hydrosilylation.
%I ACS Publications