%0 Journal Article %A Kaźmierczak, Joanna %A Kuciński, Krzysztof %A Lewandowski, Dariusz %A Hreczycho, Grzegorz %D 2019 %T Ru-Catalyzed Dehydrogenative Silylation of POSS-Silanols with Hydrosilanes: Its Introduction to One-Pot Synthesis %U https://acs.figshare.com/articles/journal_contribution/Ru-Catalyzed_Dehydrogenative_Silylation_of_POSS-Silanols_with_Hydrosilanes_Its_Introduction_to_One-Pot_Synthesis/7575587 %R 10.1021/acs.inorgchem.8b02645.s001 %2 https://acs.figshare.com/ndownloader/files/14072375 %K dehydrogenative %K one-pot procedure %K Introduction %K functionalized silsesquioxanes %K usefulness %K Hydrosilane %K SiH-containing silsesquioxanes %K siloxane moiety %K POSS-silanol %K O-silylation %K access %K derivative %K hydrosilane %K approach %K POSS-Silanol %K CO %K hydrosilylation %K Ru-Catalyzed Dehydrogenative Silylation %K Ru 3 %K aid %K ruthenium dodecacarbonyl catalyst %K SQ %K One-Pot Synthesis %K synthesis %X A commercially available and stable ruthenium dodecacarbonyl catalyst (Ru3(CO)12) allows very efficient and convenient access to functionalized silsesquioxanes (SQs) containing siloxane moiety (Si–O–Si) via dehydrogenative coupling of POSS-silanols with hydrosilanes. With the aid of SiH-containing silsesquioxanes, an unprecedented one-pot procedure has been revealed, and the usefulness of this approach was demonstrated by the synthesis of various derivatives via O-silylation, as well as CC and CN hydrosilylation. %I ACS Publications