10.1021/acs.inorgchem.8b02645.s001 Joanna Kaźmierczak Joanna Kaźmierczak Krzysztof Kuciński Krzysztof Kuciński Dariusz Lewandowski Dariusz Lewandowski Grzegorz Hreczycho Grzegorz Hreczycho Ru-Catalyzed Dehydrogenative Silylation of POSS-Silanols with Hydrosilanes: Its Introduction to One-Pot Synthesis American Chemical Society 2019 dehydrogenative one-pot procedure Introduction functionalized silsesquioxanes usefulness Hydrosilane SiH-containing silsesquioxanes siloxane moiety POSS-silanol O-silylation access derivative hydrosilane approach POSS-Silanol CO hydrosilylation Ru-Catalyzed Dehydrogenative Silylation Ru 3 aid ruthenium dodecacarbonyl catalyst SQ One-Pot Synthesis synthesis 2019-01-10 21:04:20 Journal contribution https://acs.figshare.com/articles/journal_contribution/Ru-Catalyzed_Dehydrogenative_Silylation_of_POSS-Silanols_with_Hydrosilanes_Its_Introduction_to_One-Pot_Synthesis/7575587 A commercially available and stable ruthenium dodecacarbonyl catalyst (Ru<sub>3</sub>(CO)<sub>12</sub>) allows very efficient and convenient access to functionalized silsesquioxanes (SQs) containing siloxane moiety (Si–O–Si) via dehydrogenative coupling of POSS-silanols with hydrosilanes. With the aid of SiH-containing silsesquioxanes, an unprecedented one-pot procedure has been revealed, and the usefulness of this approach was demonstrated by the synthesis of various derivatives via O-silylation, as well as CC and CN hydrosilylation.