10.1021/acs.inorgchem.8b02645.s001
Joanna Kaźmierczak
Joanna
Kaźmierczak
Krzysztof Kuciński
Krzysztof
Kuciński
Dariusz Lewandowski
Dariusz
Lewandowski
Grzegorz Hreczycho
Grzegorz
Hreczycho
Ru-Catalyzed Dehydrogenative Silylation of POSS-Silanols
with Hydrosilanes: Its Introduction to One-Pot Synthesis
American Chemical Society
2019
dehydrogenative
one-pot procedure
Introduction
functionalized silsesquioxanes
usefulness
Hydrosilane
SiH-containing silsesquioxanes
siloxane moiety
POSS-silanol
O-silylation
access
derivative
hydrosilane
approach
POSS-Silanol
CO
hydrosilylation
Ru-Catalyzed Dehydrogenative Silylation
Ru 3
aid
ruthenium dodecacarbonyl catalyst
SQ
One-Pot Synthesis
synthesis
2019-01-10 21:04:20
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Ru-Catalyzed_Dehydrogenative_Silylation_of_POSS-Silanols_with_Hydrosilanes_Its_Introduction_to_One-Pot_Synthesis/7575587
A commercially available and stable
ruthenium dodecacarbonyl catalyst
(Ru<sub>3</sub>(CO)<sub>12</sub>) allows very efficient and convenient
access to functionalized silsesquioxanes (SQs) containing siloxane
moiety (Si–O–Si) via dehydrogenative coupling of POSS-silanols
with hydrosilanes. With the aid of SiH-containing silsesquioxanes,
an unprecedented one-pot procedure has been revealed, and the usefulness
of this approach was demonstrated by the synthesis of various derivatives
via O-silylation, as well as CC and CN hydrosilylation.