10.1021/jacs.8b11998.s002
Peng Yang
Peng
Yang
Wenli Zhao
Wenli
Zhao
Aleksander Shkurenko
Aleksander
Shkurenko
Youssef Belmabkhout
Youssef
Belmabkhout
Mohamed Eddaoudi
Mohamed
Eddaoudi
Xiaochen Dong
Xiaochen
Dong
Husam N. Alshareef
Husam N.
Alshareef
Niveen M. Khashab
Niveen M.
Khashab
Polyoxometalate–Cyclodextrin
Metal–Organic
Frameworks: From Tunable Structure to Customized Storage Functionality
American Chemical Society
2019
POT-CD
building blocks
MBB
POM
Customized Storage Functionality Self-assembly
POM-CD-MOF
Li storage behavior
PW 12 O 40
γ- CD MOF
material
α- CD MOF
P 10 Pd 15.5 O 50
POP-CD
2019-01-04 00:00:00
Dataset
https://acs.figshare.com/articles/dataset/Polyoxometalate_Cyclodextrin_Metal_Organic_Frameworks_From_Tunable_Structure_to_Customized_Storage_Functionality/7565651
Self-assembly
allows structures to organize themselves into regular
patterns by using local forces to find the lowest-energy configuration.
However, assembling organic and inorganic building blocks in an ordered
framework remains challenging due to difficulties in rationally
interfacing two dissimilar materials. Herein, the ensemble of polyoxometalates
(POMs) and cyclodextrins (CDs) as molecular building blocks (MBBs)
has yielded two unprecedented POM-CD-MOFs, namely [PW<sub>12</sub>O<sub>40</sub>]<sup>3–</sup> and α-CD MOF (<b>POT-CD</b>) as well as [P<sub>10</sub>Pd<sub>15.5</sub>O<sub>50</sub>]<sup>19–</sup> and γ-CD MOF (<b>POP-CD</b>), with distinct
properties not shared by their isolated parent MBBs. Markedly, the <b>POT-CD</b> features a nontraditional enhanced Li storage behavior
by virtue of a unique “amorphization and pulverization”
process. This opens the door to a new generation of hybrid materials
with tuned structures and customized functionalities.