Mao, Shuai Chen, Zhengkai Wang, Lu Khadka, Daulat Bikram Xin, Minhang Li, Pengfei Zhang, San-Qi Synthesis of Aryl Trimethylstannane via BF<sub>3</sub>·OEt<sub>2</sub>‑Mediated Cross-Coupling of Hexaalkyl Distannane Reagent with Aryl Triazene at Room Temperature BF<sub>3</sub>·OEt<sub>2</sub>-mediated cross-coupling of (SnMe<sub>3</sub>)<sub>2</sub> with aryl triazene offers a new strategy for the synthesis of aryl stannane. A variety of synthetically useful aryl trimethylstannanes were produced in moderate to good yields with this metal-free approach. One-pot sequential Stille cross-coupling with different aryl bromides provides a short entry to both symmetrical and unsymmetrical biaryl compounds. BF;aryl trimethylstannanes;metal-free approach;Hexaalkyl Distannane Reagent;Aryl Trimethylstannane;SnMe 3;aryl triazene;aryl stannane;OEt;One-pot sequential Stille cross-coupling;unsymmetrical biaryl compounds;aryl bromides;Aryl Triazene 2018-12-12
    https://acs.figshare.com/articles/journal_contribution/Synthesis_of_Aryl_Trimethylstannane_via_BF_sub_3_sub_OEt_sub_2_sub_Mediated_Cross-Coupling_of_Hexaalkyl_Distannane_Reagent_with_Aryl_Triazene_at_Room_Temperature/7505684
10.1021/acs.joc.8b02766.s001