%0 Journal Article %A Davis-Gilbert, Zachary W. %A Kawakita, Kento %A Blechschmidt, Daniel R. %A Tsurugi, Hayato %A Mashima, Kazushi %A Tonks, Ian A. %D 2018 %T In Situ Catalyst Generation and Benchtop-Compatible Entry Points for TiII/TiIV Redox Catalytic Reactions %U https://acs.figshare.com/articles/journal_contribution/In_Situ_Catalyst_Generation_and_Benchtop-Compatible_Entry_Points_for_Ti_sup_II_sup_Ti_sup_IV_sup_Redox_Catalytic_Reactions/7056146 %R 10.1021/acs.organomet.8b00474.s001 %2 https://acs.figshare.com/ndownloader/files/12977045 %K imine %K Ti-catalyzed oxidative nitrene transfer reactions %K catalyst systems %K TiCl 4 %K IV %K II %K THF %K entry point %K Situ Catalyst Generation %K catalyst system %K Benchtop-Compatible Entry Points %X The development of several in situ generated catalyst systems for Ti-catalyzed oxidative nitrene transfer reactions is reported. The simplest and widely applicable catalyst system, TiCl4(THF)2/Zn0, can be set up on the benchtop under air. This system uses commercially available reagents and can be used as an entry point for TiII/TiIV multicomponent redox reactions for the synthesis of pyrroles, α,γ-unsaturated imines, α,β-unsaturated imines, cyclopropylimines, and arenes. %I ACS Publications