%0 Journal Article
%A Davis-Gilbert, Zachary
W.
%A Kawakita, Kento
%A Blechschmidt, Daniel R.
%A Tsurugi, Hayato
%A Mashima, Kazushi
%A Tonks, Ian A.
%D 2018
%T In Situ Catalyst Generation and Benchtop-Compatible
Entry Points for TiII/TiIV Redox Catalytic Reactions
%U https://acs.figshare.com/articles/journal_contribution/In_Situ_Catalyst_Generation_and_Benchtop-Compatible_Entry_Points_for_Ti_sup_II_sup_Ti_sup_IV_sup_Redox_Catalytic_Reactions/7056146
%R 10.1021/acs.organomet.8b00474.s001
%2 https://acs.figshare.com/ndownloader/files/12977045
%K imine
%K Ti-catalyzed oxidative nitrene transfer reactions
%K catalyst systems
%K TiCl 4
%K IV
%K II
%K THF
%K entry point
%K Situ Catalyst Generation
%K catalyst system
%K Benchtop-Compatible Entry Points
%X The development of several in situ
generated catalyst systems for
Ti-catalyzed oxidative nitrene transfer reactions is reported. The
simplest and widely applicable catalyst system, TiCl4(THF)2/Zn0, can be set up on the benchtop under air.
This system uses commercially available reagents and can be used as
an entry point for TiII/TiIV multicomponent
redox reactions for the synthesis of pyrroles, α,γ-unsaturated
imines, α,β-unsaturated imines, cyclopropylimines, and
arenes.
%I ACS Publications