Fluoro- and Chloroferrocene: From 2- to 3‑Substituted
Derivatives
Mehdi Tazi
Madani Hedidi
William Erb
Yury S. Halauko
Oleg A. Ivashkevich
Vadim E. Matulis
Thierry Roisnel
Vincent Dorcet
Ghenia Bentabed-Ababsa
Florence Mongin
10.1021/acs.organomet.8b00384.s001
https://acs.figshare.com/articles/journal_contribution/Fluoro-_and_Chloroferrocene_From_2-_to_3_Substituted_Derivatives/6798809
The
ferrocene halogen “dance” has been deemed hardly
controllable. Here, we describe the first efficient examples of this
reaction. Conversion of 1-fluoro-2-iodo (or 1-chloro-2-iodo) to 1-fluoro-3-iodo
(or 1-chloro-3-iodo) ferrocenes was ensured by suitably protecting
the free 5-position.
2018-07-10 14:03:35
1- fluoro -2-iodo
1- chloro -3-iodo ferrocenes
1- fluoro -3-iodo
1- chloro -2-iodo
5- position