%0 Journal Article %A Song, Chao %A Yang, Chen %A Zeng, Hua %A Zhang, Wenjing %A Guo, Shan %A Zhu, Jin %D 2018 %T Rh(III)-Catalyzed Enaminone-Directed C–H Coupling with α‑Diazo-α-phosphonoacetate for Reactivity Discovery: Fluoride-Mediated Dephosphonation for C–C Coupling Reactions %U https://acs.figshare.com/articles/journal_contribution/Rh_III_-Catalyzed_Enaminone-Directed_C_H_Coupling_with_Diazo-_-phosphonoacetate_for_Reactivity_Discovery_Fluoride-Mediated_Dephosphonation_for_C_C_Coupling_Reactions/6591656 %R 10.1021/acs.orglett.8b01406.s001 %2 https://acs.figshare.com/ndownloader/files/12080264 %K fluoride-mediated %K dephosphonation %K Rh %K α- diazo -α-phosphonoacetate %K Enaminone-Directed %K ester synthesis %K reactivity %K identification %K benzaldehyde %K Diazo %K α- phosphonoacetate %K enaminone-directed %K hydroxy %K Reactivity Discovery %K -1-naphthoate %K Fluoride-Mediated Dephosphonation %K 4- %K Intermolecular %X Rh­(III)-catalyzed enaminone-directed C–H coupling with α-diazo-α-phosphonoacetate has been used for the identification of fluoride-mediated dephosphonation C–C coupling reactivity for the synthesis of 4-hydroxy-1-naphthoates. Intermolecular C–C coupling of α-phosphonoacetate and benzaldehyde for (E)-selective α,β-unsaturated ester synthesis has also been achieved. %I ACS Publications