Rh(III)-Catalyzed Enaminone-Directed C–H Coupling with α‑Diazo-α-phosphonoacetate for Reactivity Discovery: Fluoride-Mediated Dephosphonation for C–C Coupling Reactions Chao Song Chen Yang Hua Zeng Wenjing Zhang Shan Guo Jin Zhu 10.1021/acs.orglett.8b01406.s001 https://acs.figshare.com/articles/journal_contribution/Rh_III_-Catalyzed_Enaminone-Directed_C_H_Coupling_with_Diazo-_-phosphonoacetate_for_Reactivity_Discovery_Fluoride-Mediated_Dephosphonation_for_C_C_Coupling_Reactions/6591656 Rh­(III)-catalyzed enaminone-directed C–H coupling with α-diazo-α-phosphonoacetate has been used for the identification of fluoride-mediated dephosphonation C–C coupling reactivity for the synthesis of 4-hydroxy-1-naphthoates. Intermolecular C–C coupling of α-phosphonoacetate and benzaldehyde for (<i>E</i>)-selective α,β-unsaturated ester synthesis has also been achieved. 2018-06-18 21:20:59 fluoride-mediated dephosphonation Rh α- diazo -α-phosphonoacetate Enaminone-Directed ester synthesis reactivity identification benzaldehyde Diazo α- phosphonoacetate enaminone-directed hydroxy Reactivity Discovery -1-naphthoate Fluoride-Mediated Dephosphonation 4- Intermolecular