Rh(III)-Catalyzed Enaminone-Directed C–H Coupling with α‑Diazo-α-phosphonoacetate for Reactivity Discovery: Fluoride-Mediated Dephosphonation for C–C Coupling Reactions
Chao Song
Chen Yang
Hua Zeng
Wenjing Zhang
Shan Guo
Jin Zhu
10.1021/acs.orglett.8b01406.s001
https://acs.figshare.com/articles/journal_contribution/Rh_III_-Catalyzed_Enaminone-Directed_C_H_Coupling_with_Diazo-_-phosphonoacetate_for_Reactivity_Discovery_Fluoride-Mediated_Dephosphonation_for_C_C_Coupling_Reactions/6591656
Rh(III)-catalyzed
enaminone-directed C–H coupling with α-diazo-α-phosphonoacetate
has been used for the identification of fluoride-mediated dephosphonation
C–C coupling reactivity for the synthesis of 4-hydroxy-1-naphthoates.
Intermolecular C–C coupling of α-phosphonoacetate and
benzaldehyde for (<i>E</i>)-selective α,β-unsaturated
ester synthesis has also been achieved.
2018-06-18 21:20:59
fluoride-mediated
dephosphonation
Rh
α- diazo -α-phosphonoacetate
Enaminone-Directed
ester synthesis
reactivity
identification
benzaldehyde
Diazo
α- phosphonoacetate
enaminone-directed
hydroxy
Reactivity Discovery
-1-naphthoate
Fluoride-Mediated Dephosphonation
4-
Intermolecular