10.1021/acs.inorgchem.7b03108.s001
Xiao-Dong Yang
Xiao-Dong
Yang
Rui Zhu
Rui
Zhu
Li Sun
Li
Sun
Rui-Yun Guo
Rui-Yun
Guo
Jie Zhang
Jie
Zhang
Phototriggered Mechanical Movement in A Bipyridinium-based
Coordination Polymer Powered by Electron Transfer
American Chemical Society
2018
Phototriggered Mechanical Movement
occurrence
decorrelation
bipyridinium-based coordination polymer
CT state
PET reaction
deformation
electron-deficient bipyridinium core
Electron Transfer Photomechanical movement
Bipyridinium-based Coordination Polymer Powered
electron-rich phenylcarboxylate components
2018-02-09 13:11:35
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Phototriggered_Mechanical_Movement_in_A_Bipyridinium-based_Coordination_Polymer_Powered_by_Electron_Transfer/5873556
Photomechanical movement
with a morphological deformation has been achieved in the crystalline
state of a bipyridinium-based coordination polymer. The engine “heart”
is the electron-deficient bipyridinium core sandwiched by electron-rich
phenylcarboxylate components. The decorrelation of the CT state triggered
by PET reaction in the engine “heart” promotes the occurrence
of this mechanical movement.