%0 Journal Article %A Zhang, Ming-Zhong %A Luo, Na %A Long, Rui-Yang %A Gou, Xian-Tao %A Shi, Wen-Bing %A He, Shu-Hua %A Jiang, Yong %A Chen, Jin-Yang %A Chen, Tieqiao %D 2018 %T Transition-Metal-Free Oxidative Aminooxyarylation of Alkenes: Annulations toward Aminooxylated Oxindoles %U https://acs.figshare.com/articles/journal_contribution/Transition-Metal-Free_Oxidative_Aminooxyarylation_of_Alkenes_Annulations_toward_Aminooxylated_Oxindoles/5852778 %R 10.1021/acs.joc.7b02740.s001 %2 https://acs.figshare.com/ndownloader/files/10387365 %K reaction conditions %K Transition-Metal-Free Oxidative Aminooxyarylation %K NHPI %K aminooxylated %K bond %X An efficient oxidative aminooxyarylation of alkenes under a transition-metal-free condition was described. Under the reaction conditions, N-hydroxyphthalimide (NHPI) reacted readily with N-arylacrylamides to produce cyclic products via a radical C–H functionalization process, achieving both C–O and C–C bonds formation in one pot. This reaction provided a facile access to the valuable aminooxylated oxindoles. The benzylic and α-methylene C­(sp3)-H bonds were also aminooxylated under the reaction conditions. %I ACS Publications