Lee, Hanyeong Triviño, Monica Louise T. Hwang, Soonha Kwon, Sung Hyun Lee, Seung Geol Moon, Jun Hyuk Yoo, Jungho Seo, Jeong Gil In Situ Observation of Carbon Dioxide Capture on Pseudo-Liquid Eutectic Mixture-Promoted Magnesium Oxide Eutectic mixtures of alkali nitrates are known to increase the sorption capacity and kinetics of MgO-based sorbents. Underlying principles and mechanisms for CO<sub>2</sub> capture on such sorbents have already been established; however, real-time observation of the system was not yet accomplished. In this work, we present the direct-observation of the CO<sub>2</sub> capture phenomenon on a KNO<sub>3</sub>–LiNO<sub>3</sub> eutectic mixture (EM)-promoted MgO sample, denoted as KLM, via in situ transmission electron microscopy (in situ TEM). Results revealed that the pseudoliquid EM undergoes structural rearrangement as MgCO<sub>3</sub> evolves from the surface of MgO, resulting in surface roughening and evolution of cloudy structures that stay finely distributed after regeneration. From this, we propose a nucleation and structural rearrangement scheme for MgCO<sub>3</sub> and EM, which involves the rearrangement of bulk EM to evenly distributed EM clusters due to MgCO<sub>3</sub> saturation as adsorption proceeds. We also conducted studies on the interface between EM over solid MgO and MgCO<sub>3</sub> formed during sorption, which further clarifies the interaction between MgO and EM. This study provides better insight into the sorption and regeneration mechanism, as well as the structural rearrangements involved in EM-promoted sorbents by basing not only on intrinsic evolutions but also on real-time observation of the system as a whole. Carbon Dioxide Capture;MgO;TEM;MgCO 3;sorption;MgCO 3 saturation;Pseudo-Liquid Eutectic Mixture-Promoted Magnesium Oxide Eutectic mixtures;EM;KNO;KLM;transmission electron microscopy;CO 2;sorbent;rearrangement 2017-12-26
    https://acs.figshare.com/articles/media/In_Situ_Observation_of_Carbon_Dioxide_Capture_on_Pseudo-Liquid_Eutectic_Mixture-Promoted_Magnesium_Oxide/5768235
10.1021/acsami.7b14256.s003