10.1021/acs.orglett.7b03296.s001
Lujia Mao
Lujia
Mao
Rüdiger Bertermann
Rüdiger
Bertermann
Simon G. Rachor
Simon G.
Rachor
Kálmán J. Szabó
Kálmán J.
Szabó
Todd B. Marder
Todd B.
Marder
Palladium-Catalyzed Oxidative Borylation of Allylic
C–H Bonds in Alkenes
American Chemical Society
2017
alkene
transformation exhibits
pincer
allylic
allyl-Bpin products
Palladium-Catalyzed Oxidative Borylation
borylation
2017-11-30 17:05:39
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Palladium-Catalyzed_Oxidative_Borylation_of_Allylic_C_H_Bonds_in_Alkenes/5650171
This communication
describes an efficient palladium pincer complex-catalyzed
allylic C–H borylation of alkenes. The transformation exhibits
high regio- and stereoselectivity with a variety of linear alkenes.
A synthetically useful feature of this allylic C–H borylation
method is that all allyl-Bpin products can be isolated in usually
high yields. Preliminary mechanistic studies indicate that this C–H
borylation reaction proceeds via Pd(IV) pincer complex intermediates.