TY - DATA T1 - Development of Sustainable Thermosets from Cardanol-based Epoxy Prepolymer and Ionic Liquids PY - 2017/08/11 AU - Thi Khanh Ly Nguyen AU - Sébastien Livi AU - Bluma G. Soares AU - Guilherme M. O. Barra AU - Jean-François Gérard AU - Jannick Duchet-Rumeau UR - https://acs.figshare.com/articles/journal_contribution/Development_of_Sustainable_Thermosets_from_Cardanol-based_Epoxy_Prepolymer_and_Ionic_Liquids/5305501 DO - 10.1021/acssuschemeng.7b02292.s001 L4 - https://acs.figshare.com/ndownloader/files/9090448 KW - Ionic Liquids KW - surface energy KW - glass transition temperature KW - biobased KW - Cardanol-based Epoxy Prepolymer KW - phosphinate counteranions KW - IL KW - Sustainable Thermosets KW - Ionic liquids KW - prepolymer N2 - In this work, the development of new biobased epoxy networks using phosphonium-based ionic liquids combined with dicyanamide and phosphinate counteranions as initiators of epoxy prepolymers was compared with a biobased epoxy–amine system. Ionic liquids (ILs) displayed high reactivity toward cardanol-based epoxy prepolymers, and the obtained biobased epoxy/IL networks highlighted a glass transition temperature of around 30 °C, an excellent thermal stability higher than 450 °C and higher hydrophobic behavior compared to biobased epoxy–amine networks. In addition, the use of a cardanol-based epoxy prepolymer as a modifier of epoxy/IL networks was also investigated. In this case, the final properties of epoxy/IL networks were improved by the presence of biobased epoxy compounds, especially their surface energy as well as their fracture toughness (+180%), suggesting a new way to develop partially biobased epoxy coatings. ER -