Levitre, Guillaume Dumoulin, Audrey Retailleau, Pascal Panossian, Armen Leroux, Frédéric R. Masson, Géraldine Asymmetric α‑Sulfonyl- and α‑Phosphoryl-Oxylation of Ketones by a Chiral Hypervalent Iodine(III) An enantioselective direct oxygenation of propiophenone derivatives mediated by a catalytic or stoichiometric amount of new chiral non-<i>C</i>2-symmetric iodoarenes­(III) is reported. The reaction gives an easy entry to optically active α-sulfonyl- and α-phosphoryl oxyketones in respectable yields and enantioselectivities. oxygenation;Phosphoryl-Oxylation;α- sulfonyl;propiophenone derivatives;enantioselective;iodoarene;Asymmetric;C 2-;enantioselectivitie;stoichiometric amount;Chiral;α- phosphoryl oxyketones;Ketone;entry;Iodine;chiral;yield;Hypervalent;Sulfonyl 2017-07-21
    https://acs.figshare.com/articles/journal_contribution/Asymmetric_Sulfonyl-_and_Phosphoryl-Oxylation_of_Ketones_by_a_Chiral_Hypervalent_Iodine_III_/5261617
10.1021/acs.joc.7b01597.s001