Flexible Light-Weight Lithium-Ion-Conducting Inorganic–Organic
Composite Electrolyte Membrane
Dorsasadat Safanama
Stefan Adams
10.1021/acsenergylett.7b00204.s001
https://acs.figshare.com/articles/journal_contribution/Flexible_Light-Weight_Lithium-Ion-Conducting_Inorganic_Organic_Composite_Electrolyte_Membrane/4905632
A fast
Li<sup>+</sup>-ion-conducting membrane is the key component
behind successful performance of an aqueous or hybrid Li–air
battery. Currently available ceramic ionic conductors are hardly scalable,
difficult to seal, brittle, and electrochemically unstable against
the commonly used catholytes. In this work, an easily scalable high-performance
hybrid inorganic–organic membrane is realized that consists
of NASICON-type Li<sub>1+<i>x</i></sub>Al<sub><i>x</i></sub>Ge<sub>2–<i>x</i></sub>(PO<sub>4</sub>)<sub>3</sub> (LAGP) as the fast ion-conducting ceramic filler within a
high-stability polymer blend. The as-prepared hybrid membrane exhibits
high ionic conductivity of 1.0 × 10<sup>–4</sup> S cm<sup>–1</sup> with chemical stability in both neutral and acidified
lithium chloride solutions. Energy efficiency of >93% under a current
density of 0.03 mA cm<sup>–2</sup> for aqueous/hybrid Li–air
batteries enabled by this hybrid anode-protecting membrane is demonstrated.
2017-04-20 00:00:00
Flexible Light-Weight Lithium-Ion-Conducting
anode-protecting membrane
membrane exhibits
cm
energy efficiency
chemical stability
scalable
high-stability polymer blend
ion-conducting membrane
PO 4
LAGP
lithium chloride solutions