Unprecedented Li<sup>+</sup> Exchange in an Anionic
Metal–Organic Framework: Significantly Enhanced Gas Uptake
Capacity
Bo Liu
Rui Zhang
Chun-Yang Pan
Hai-Long Jiang
10.1021/acs.inorgchem.7b00538.s002
https://acs.figshare.com/articles/dataset/Unprecedented_Li_sup_sup_Exchange_in_an_Anionic_Metal_Organic_Framework_Significantly_Enhanced_Gas_Uptake_Capacity/4818820
We herein report
the first example of Li<sup>+</sup> exchanged with both the guest
H<sub>2</sub>N(Me)<sub>2</sub><sup>+</sup> cations located in the
channels and the coordinated metal ions from an anionic metal–organic
framework (MOF), leading to significant enhancement of the pore volume
and gas sorption abilities of the exchanged MOF. Furthermore, both
MOFs before and after Li<sup>+</sup> exchange show good selective
adsorption for CO<sub>2</sub> over CH<sub>4</sub>.
2017-04-05 17:25:11
exchange show
Unprecedented Li
CH 4
metal ions
pore volume
gas sorption abilities
CO 2
MOF
Enhanced Gas Uptake Capacity