10.1021/acs.inorgchem.6b03160.s001
Yulia Yu. Enakieva
Yulia Yu.
Enakieva
Marina V. Volostnykh
Marina V.
Volostnykh
Sergey E. Nefedov
Sergey E.
Nefedov
Gayane A. Kirakosyan
Gayane A.
Kirakosyan
Yulia G. Gorbunova
Yulia G.
Gorbunova
Aslan Yu. Tsivadze
Aslan Yu.
Tsivadze
Alla G. Bessmertnykh-Lemeune
Alla G.
Bessmertnykh-Lemeune
Christine Stern
Christine
Stern
Roger Guilard
Roger
Guilard
Gallium(III) and Indium(III) Complexes with <i>meso</i>-Monophosphorylated Porphyrins: Synthesis and Structure. A First Example of Dimers Formed
by the Self-Assembly of <i>meso</i>-Porphyrinylphosphonic
Acid Monoester
American Chemical Society
2017
31 P NMR
self-assembled dimer
Monophosphorylated Porphyrins
X-ray diffraction
porphyrin molecules
phosphonic acids
phosphonate substituent
1 H
X-ray structure
meso
oxygen atom
gallium
First Example
UV
2017-02-14 17:34:28
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Gallium_III_and_Indium_III_Complexes_with_i_meso_i_-Monophosphorylated_Porphyrins_Synthesis_and_Structure_A_First_Example_of_Dimers_Formed_by_the_Self-Assembly_of_i_meso_i_-Porphyrinylphosphonic_Acid_Monoester/4650289
The synthesis and
structural characterization, both in solution by means of <sup>1</sup>H and <sup>31</sup>P NMR and UV–vis spectroscopies and in
the solid state by X-ray diffraction on single crystal, of a series
of gallium(III) and indium(III) <i>meso</i>-mono(diethoxyphosphoryl)porphyrins
bearing different peripheral substituents as well as the corresponding
monoesters and phosphonic acids are reported. This work describes
the first example of the X-ray structure of a self-assembled dimer
formed via strong binding between the oxygen atom of the phosphonate
substituent and the gallium(III) cations of adjacent porphyrin molecules
[Ga–O = 1.9708(13) Å].