%0 Generic
%A Chen, Ting
%A Huo, Peng
%A Hou, Jin-Le
%A Xu, Jing
%A Zhu, Qin-Yu
%A Dai, Jie
%D 2016
%T Confinement
Effects of Metal–Organic Framework on the Formation of Charge-Transfer
Tetrathiafulvalene Dimers
%U https://acs.figshare.com/articles/dataset/Confinement_Effects_of_Metal_Organic_Framework_on_the_Formation_of_Charge-Transfer_Tetrathiafulvalene_Dimers/4275872
%R 10.1021/acs.inorgchem.6b02062.s002
%2 https://acs.figshare.com/ndownloader/files/6970874
%K confinement effect
%K isostructural 2- D polymers
%K Complexes 1
%K Charge-Transfer Tetrathiafulvalene Dimers
%K O bridge
%K TTF dimers
%K Confinement Effects
%K Cd compound 3
%K μ 2
%K electron transfer
%K 3- D MOF
%K H 2 O
%K TTF ligand
%K CP
%K TTF coordination polymers
%K tetranuclear cluster nodes
%K charge transfer
%K intradimer interaction
%K transition metal coordination polymers
%K photocurrent response property
%K 3 features
%K 2- D Cd compound 2
%K TTF dimers show
%X Three
transition metal coordination polymers (CPs) based on the
redox-active dimethylthio-tetrathiafulvalene-bicarboxylate
(L) and 1,3-bi(4-pyridyl)propane (bpp) ligands, formulated as
[MnL(bpp)]n (1), [CdL(bpp)]n (2), and [Cd2L(bpp)2(H2O)(C2O4)0.5]n·n(ClO4)·n(H2O) (3),
are crystallographically characterized. Complexes 1 and 2 are isostructural 2-D polymers, and 3 features
an unusual 3-D metal–organic framework (MOF). The 3-D MOF is
constructed from tetranuclear cluster nodes built through the μ2-O bridge of the TTF ligand, which is first found for TTF
coordination polymers. It is found that the channel generated by the
3-D MOF exerts a confinement effect on the formation of TTF dimers.
The TTF dimers show strong intradimer interaction with partial electron
transfer or charge transfer, and hence, the Cd compound 3 has relatively good photocurrent response property in comparison
with that of 2-D Cd compound 2.
%I ACS Publications