10.1021/acs.inorgchem.6b01828.s002
Yu Fang
Yu
Fang
Wei Gong
Wei
Gong
Lujia Liu
Lujia
Liu
Yan Liu
Yan
Liu
Yong Cui
Yong
Cui
Triple-Stranded Cluster Helicates for the Selective
Catalytic Oxidation of C–H Bonds
American Chemical Society
2016
C 2
ortho-substitued biphenol
copper species
Selective Catalytic Oxidation
helicate
entrapping metals
heptametallic dicubane cores
hexadentate Schiff-base ligand
Triple-Stranded Cluster Helicates
2016-09-27 13:18:44
Dataset
https://acs.figshare.com/articles/dataset/Triple-Stranded_Cluster_Helicates_for_the_Selective_Catalytic_Oxidation_of_C_H_Bonds/3860364
Triple-stranded
cluster helicates with heptametallic dicubane cores are synthesized
by entrapping metals in the cavities of linear triple helicates based
on a <i>C</i><sub>2</sub>-symmetrical hexadentate Schiff-base
ligand of ortho-substitued biphenol. The helicates are stable in both
the solution and solid states, and the copper species could selectively
catalyze the oxidation of C–H bonds of alkanes to ketones.