Single Component Lanthanide Hybrids Based on Metal–Organic Framework for Near-Ultraviolet White Light LED Yan-Wu Zhao Fu-Qiang Zhang Xian-Ming Zhang 10.1021/acsami.6b07724.s001 https://acs.figshare.com/articles/journal_contribution/Single_Component_Lanthanide_Hybrids_Based_on_Metal_Organic_Framework_for_Near-Ultraviolet_White_Light_LED/3795276 Near-UV single-phase white-light phosphor (Eu<sub>0.045</sub>Tb<sub>0.955</sub>CPOMBA/La<sub>0.6</sub>Eu<sub>0.1</sub>Tb<sub>0.3</sub>CPOMBA) based on metal–organic framework was prepared by in situ doping isostructural lanthanide MOF with Eu<sup>3+</sup> and Tb<sup>3+</sup>, and it is found that the energy can effectively transfer from organic ligand to lanthanides, which can overcome weak absorption under direct excitation of lanthanide ions due to the forbidden f–f transitions. The photoluminescence and thermostability of the new MOF phosphor are investigated, and effective white-light emission is achieved under 365 and 380 nm excitations. By employing Eu<sub>0.045</sub>Tb<sub>0.955</sub>CPOMBA as phosphor, we fabricated a near-ultraviolet white-light-emitting diode (n-UV WLED) (365 nm) with low CCT (5733 K), high CRI (<i>R</i><sub>a</sub> = 73.4), and CIE chromaticity coordinate (0.3264, 0.3427). This approach may open new perspectives for developing single-phase UV phosphors. 2016-08-25 00:00:00 CCT doping isostructural lanthanide MOF Near-Ultraviolet White Light LED Near-UV single-phase white-light phosphor Eu 0.045 Tb 0.955 CPOMBA 380 nm excitations lanthanide ions CIE chromaticity single-phase UV phosphors Single Component Lanthanide Hybrids CRI n-UV WLED near-ultraviolet white-light-emitting diode white-light emission MOF phosphor