%0 Journal Article
%A Lefort, Laurent
%A Lachicotte, Rene J.
%A Jones, William D.
%D 1998
%T Insertion of SO2 into the Metal−Carbon Bonds of
Rhodium and Iridium Compounds, and Reactivity of the
SO2-Inserted Species
%U https://acs.figshare.com/articles/journal_contribution/Insertion_of_SO_sub_2_sub_into_the_Metal_Carbon_Bonds_of_Rhodium_and_Iridium_Compounds_and_Reactivity_of_the_SO_sub_2_sub_-Inserted_Species/3781566
%R 10.1021/om971030m.s001
%2 https://acs.figshare.com/ndownloader/files/5892531
%K sulfinate
%K sulfinic acid
%K Inserted Species Sulfur dioxide
%X Sulfur dioxide has been found to insert into the metal−carbon
bonds of both rhodium and
iridium alkyl and aryl complexes. The sulfinate ligand can be
removed with a strong acid
such as HCl, generating free sulfinic acid. Acids with weakly
coordinating anions protonate
the sulfinate oxygen, but the sulfinic acid remains bound to the metal
center. Added sulfinic
acids can exchange with the coordinated sulfinate group.
%I ACS Publications