%0 Journal Article
%A Jamison, Gregory M.
%A Saunders, Randall S.
%A Wheeler, David R.
%A Alam, Todd M.
%A McClain, Mark D.
%A Loy, Douglas A.
%A Ziller, Joseph W.
%D 1996
%T Isolation and Characterization of the Molybdenum
Alkylidyne Complex
[(F3C)Me2CO]2Mo(C-t-Bu)[N(Ar)PC(H)(CMe2Ph)] and Its
Conversion to a Phosphamolybdacyclobutene
%U https://acs.figshare.com/articles/journal_contribution/Isolation_and_Characterization_of_the_Molybdenum_Alkylidyne_Complex_F_sub_3_sub_C_Me_sub_2_sub_CO_sub_2_sub_Mo_C-_i_t_i_-Bu_N_Ar_P_C_H_CMe_sub_2_sub_Ph_and_Its_Conversion_to_a_Phosphamolybdacyclobutene/3777963
%R 10.1021/om960418z.s002
%2 https://acs.figshare.com/ndownloader/files/5888856
%K Alkylidyne 3 b
%K 3 b
%K Ph
%K Complexes 3 b
%K molybdenum alkylidene 1 b
%K Bu
%K CO
%K Mo
%K 2 C 6 H 3
%X Novel molybdenum alkylidyne
[(F3C)Me2CO]2Mo(C-t-Bu)[N(Ar)PC(H)(CMe2Ph)]
(Ar = 2,6-(i-Pr)2C6H3; 3b) is formed
in the reaction of tert-butylphosphaalkyne 2 with molybdenum alkylidene 1b.
Alkylidyne
3b, which contains a formal
(phosphaalkenyl)amido
ligand, rearranges quantitatively at elevated temperature to form the alkoxide-shifted phosphamolybdacyclobutene 4b. Complexes 3b and 4b
have been fully
characterized by spectroscopic and X-ray crystallographic analysis; cleavage of the P⋮C-t-Bu triple
bond
in complex 3b is confirmed.
%I ACS Publications