%0 Generic
%A van der Drift, Robert C.
%A Bouwman, Elisabeth
%A Drent, Eite
%A Kooijman, Huub
%A Spek, Anthony L.
%A Bart van Oort, A.
%A Mul, Wilhelmus P.
%D 2002
%T Structure, Dynamic Behavior, and Catalytic Activity of a
Novel Ruthenium Cyclopentadienyl Complex with a
Tridentate P,P,O Ligand
%U https://acs.figshare.com/articles/dataset/Structure_Dynamic_Behavior_and_Catalytic_Activity_of_a_Novel_Ruthenium_Cyclopentadienyl_Complex_with_a_Tridentate_P_i_i_P_i_i_O_Ligand/3772440
%R 10.1021/om020218p.s001
%2 https://acs.figshare.com/ndownloader/files/5881227
%K NMR study corroborates
%K Tridentate P
%K allylic alcohols
%K ruthenium cyclopentadienyl
%K Complex 3
%K O Ligand Reaction
%K Dynamic Behavior
%K CH
%K methoxyphenyl
%K 1 H NMR spectra
%K Catalytic Activity
%K carbonyl compounds
%K Novel Ruthenium Cyclopentadienyl Complex
%X Reaction of 1,2-bis(bis(o-methoxyphenyl)phosphino)ethane (o-MeO-dppe) with [RuClCp(PPh3)2] (1) at 135 °C results in the formation of (η5-cyclopentadienyl)[1-(bis(o-methoxyphenyl)phosphino-κP)-2-((o-methoxyphenyl)(o-phenolato-κO)phosphino-κP)ethane]ruthenium(II) ([RuCp(tappe)]; 3), which constitutes the first example of a ruthenium cyclopentadienyl
complex with a tridentate P,P,O ligand. The X-ray structure of 3 has been determined to
elucidate its solid-state structure, which shows evidence for a CH/π interaction. An NMR
study corroborates this finding, and temperature-dependent 31P and 1H NMR spectra reveal
the dynamic behavior of 3 in solution. Complex 3 shows catalytic activity in the isomerization
of allylic alcohols to carbonyl compounds.
%I ACS Publications