%0 Journal Article
%A Ashe, Arthur J.
%A Fang, Xiangdong
%A Kampf, Jeff W.
%D 2001
%T 1-Arsanaphthalene. The Structure of
Tricarbonyl(2-trimethylsilyl-1-arsanaphthalene)molybdenum
%U https://acs.figshare.com/articles/journal_contribution/1-Arsanaphthalene_The_Structure_of_Tricarbonyl_2-trimethylsilyl-1-arsanaphthalene_molybdenum/3765417
%R 10.1021/om010100t.s002
%2 https://acs.figshare.com/ndownloader/files/5872830
%K BF
%K C 5
%K crystal structure
%K η 6
%K exchange reaction
%K Arsanaphthalene
%K Mo
%K AsCl 3
%K DBU
%X 1-Arsanaphthalene (3) and 2-trimethylsilyl-1-arsanaphthalene (4) have been prepared from
the corresponding 1,4-dihydro-1,1-dimethyl-1-stannanaphthalenes 7 and 17, respectively,
via an exchange reaction with AsCl3 followed by dehydrohalogenation by DBU. Both 3 and
4 are in mobile equilibrium with their head-to-head Diels−Alder dimers. The reaction of 4
with Mo(CO)3(Py)3 and BF3·OEt2 affords Mo(CO)3 complex 5. The crystal structure of 5 shows
that the Mo(CO)3 group is η6-bound to the C5As ring of the arsanaphthalene.
%I ACS Publications